Ihe onwunwe

Mechanical akarana-ekere òkè dị oke mkpa n'izere ntapu maka ọtụtụ ụlọ ọrụ dị iche iche. Na mmiri ụlọ ọrụ e nweremgbapụta n'ibu akàrà, na-atụgharị aro n'ibu akara. Na mmanụ na gas ụlọ ọrụ e nwerekatrij n'ibu akàrà,kewaa n'ibu akàrà ma ọ bụ akọrọ gas n'ibu akàrà. N'ime ụlọ ọrụ ụgbọ ala, enwere akara akara mmiri. Na kemịkalụ ụlọ ọrụ e nwere igwekota n'ibu akàrà (agitator n'ibu akàrà) na compressor n'ibu akàrà.

Dabere dị iche iche iji ọnọdụ, ọ na-achọ n'ibu akara ngwọta na dị iche iche ihe. Enwere ọtụtụ ụdị ihe eji eme iheigwe aro akàrà dị ka seramiiki n'ibu akàrà, carbon n'ibu akàrà, Silicone carbide n'ibu akara,SSIC n'ibu akàrà naTC igwe akàrà. 

seramiiki n'ibu mgbanaka

Akara igwe seramiki

Akara igwe seramiiki bụ ihe dị oke mkpa na ngwa ụlọ ọrụ dị iche iche, emebere iji gbochie mmịpụta nke mmiri n'etiti elu abụọ, dị ka ogwe na-atụgharị na ụlọ kwụ ọtọ. A na-eji akara ndị a kpọrọ ihe nke ukwuu n'ihi nguzogide ha pụrụiche, nguzogide corrosion, na ike iguzogide oke okpomọkụ.

Ọrụ bụ isi nke seramiiki igwe akàrà bụ idobe iguzosi ike n'ezi ihe nke akụrụngwa site na igbochi mfu mmiri ma ọ bụ mmetọ. A na-eji ha n'ọtụtụ ụlọ ọrụ, gụnyere mmanụ na gas, nhazi kemịkalụ, ọgwụgwọ mmiri, ọgwụ na nhazi nri. Enwere ike ikwu na ojiji nke akàrà a juru ebe niile n'ihi ihe owuwu ha na-adịgide adịgide; A na-eme ha site na ihe seramiiki dị elu nke na-enye njirimara arụmọrụ dị elu ma e jiri ya tụnyere ihe akara ndị ọzọ.

Akara igwe seramiiki nwere ihe abụọ bụ isi: otu bụ ihu kwụ ọtọ (nke a na-ejikarị seramiiki eme ya), nke ọzọ bụ ihu igwe rotary (nke a na-ewukarị site na carbon graphite). Omume akara na-eme mgbe ejikọtara ihu abụọ ahụ site na iji ike mmiri, na-emepụta ihe mgbochi dị irè megide ntapu mmiri. Ka akụrụngwa na-arụ ọrụ, ihe nkiri na-agba mmanụ n'etiti ihu mkpuchi na-ebelata esemokwu na iyi ka ọ na-ejigide akara siri ike.

Otu ihe dị mkpa na-ekewa akara seramiiki n'ụdị ndị ọzọ bụ nguzogide ha pụtara ìhè. Ihe seramiiki nwere ezigbo ike ike nke na-enye ha ohere ịtachi obi n'ọnọdụ abrasive na-enweghị nnukwu mmebi. Nke a na-ebute akara na-adịte aka nke na-achọ obere ngbanwe ma ọ bụ nrụzi ugboro ugboro karịa nke emere site na ihe ndị dị nro.

Na mgbakwunye na iyi nguzogide, seramiiki na-egosipụtakwa nkwụsi ike nke okpomọkụ. Ha nwere ike iguzogide oke okpomọkụ na-enweghị nbibi ma ọ bụ na-efunarị arụmọrụ akara ha. Nke a na-eme ka ha dabara adaba maka ojiji na ngwa okpomọkụ dị elu ebe ihe akara ndị ọzọ nwere ike daa n'oge.

N'ikpeazụ, seramiiki n'ibu akara na-enye ezigbo ndakọrịta kemịkalụ, na-eguzogide ihe dị iche iche na-emebi emebi. Nke a na-eme ka ha bụrụ nhọrọ mara mma maka ụlọ ọrụ ndị na-ejikarị kemịkalụ siri ike na mmiri mmiri eme ihe.

Akara igwe seramiki dị mkpaakụrụngwa akaraemebere iji gbochie ntapu mmiri na akụrụngwa ụlọ ọrụ. Ngwongwo ha pụrụ iche, dị ka nguzogide iyi, nkwụsi ike ọkụ, na ndakọrịta kemịkalụ, na-eme ka ha bụrụ nhọrọ kacha amasị maka ngwa dị iche iche n'ofe ọtụtụ ụlọ ọrụ.

seramiiki anụ ahụ

Nka nka

otu

95%

99%

99.50%

Njupụta

g/cm3

3.7

3.88

3.9

Isi ike

HRA

85

88

90

Ọnụọgụ porosity

%

0.4

0.2

0.15

Ike mgbaji

MPa

250

310

350

Ọnụọgụ nke mgbasawanye okpomọkụ

10 (-6)/K

5.5

5.3

5.2

Thermal conductivity

W/MK

27.8

26.7

26

 

mgbanaka ígwè ọrụ carbon

Akara igwe igwe carbon

Mechanical carbon akara nwere ogologo akụkọ ihe mere eme. Graphite bụ isoform nke mmewere carbon. Na 1971, United States mụrụ ihe ịga nke ọma na-agbanwe agbanwe graphite n'ibu akara ihe, nke doziri ntapu nke atomic valvụ ike. Mgbe nhazi miri emi gasịrị, graphite na-agbanwe agbanwe na-aghọ ihe mkpuchi dị mma, nke a na-eme ka ọ bụrụ ihe mkpuchi carbon dị iche iche na-enwe mmetụta nke ihe mkpuchi. A na-eji akara mkpuchi carbon carbon ndị a na kemịkalụ, mmanụ ala, ụlọ ọrụ ọkụ eletrik dị ka akara mmiri mmiri dị elu.
N'ihi na a na-emepụta graphite na-agbanwe agbanwe site na mgbasawanye nke graphite gbasaa mgbe okpomọkụ dị elu, ọnụ ọgụgụ nke onye na-eme ihe na-eme ka ọ dị na graphite na-agbanwe agbanwe dị nnọọ ntakịrị, ma ọ bụghị kpamkpam, ya mere ịdị adị na nhazi nke onye na-ahụ maka intercalation nwere mmetụta dị ukwuu na àgwà. na arụmọrụ nke ngwaahịa.

Nhọrọ nke Ihe mkpuchi ihu Carbon

Onye mepụtara mbụ jiri sulfuric acid gbadoro anya dị ka oxidant na onye na-emekọrịta ihe. Otú ọ dị, mgbe etinyere ya na akara nke akụkụ ígwè, a chọtara obere sọlfọ fọdụrụ na graphite na-agbanwe agbanwe na-emebi metal kọntaktị mgbe ejiri ogologo oge mee ihe. N'ihi nke a, ụfọdụ ndị ọkà mmụta ụlọ agbalịwo imeziwanye ya, dị ka Song Kemin bụ onye họọrọ acetic acid na organic acid kama sulfuric acid. acid, na-adị nwayọọ na nitric acid, ma na-ebelata okpomọkụ ruo n'ime ụlọ, nke sitere na ngwakọta nke nitric acid na acetic acid. Site n'iji ngwakọta nke nitric acid na acetic acid dị ka onye na-etinye ya, a kwadebere graphite na-agbasaghị sọlfọ na potassium permanganate dị ka oxidant, ma jiri nwayọọ nwayọọ tinye acetic acid na nitric acid. A na-ebelata okpomọkụ na ụlọ okpomọkụ, a na-eme ngwakọta nke nitric acid na acetic acid. Mgbe ahụ, a na-agbakwunye graphite eke flake na potassium permanganate na ngwakọta a. N'okpuru mkpali mgbe niile, okpomọkụ dị 30 C. Mgbe mmeghachi omume 40min gasịrị, a na-asacha mmiri na-anọpụ iche na nke a mịrị amị na 50 ~ 60 C, a na-eme ka graphite gbasaa mgbe mgbasawanye okpomọkụ gasịrị. Usoro a na-enweta ọ dịghị vulcanization n'okpuru ọnọdụ na ngwaahịa nwere ike iru a ụfọdụ olu nke mgbasa, ka iji nweta a dịtụ ike ọdịdị nke akara ihe.

Ụdị

M106H

M120H

M106K

M120K

M106F

M120F

M106D

M120D

M254D

Ụdị

Ime ime
Epoxy resin (B1)

Ime ime
Furan resin (B1)

Phenol dị ime
Aldehyde resin (B2)

Carbon Antimon (A)

Njupụta
(g/cm³)

1.75

1.7

1.75

1.7

1.75

1.7

2.3

2.3

2.3

Ike Fractural
(Mpa)

65

60

67

62

60

55

65

60

55

Ike mkpakọ
(Mpa)

200

180

200

180

200

180

220

220

210

Isi ike

85

80

90

85

85

80

90

90

65

Porosity

<1

<1

<1

<1

<1

<1

<1.5 <1.5 <1.5

Okpomọkụ
(℃)

250

250

250

250

250

250

400

400

450

 

sic n'ibu mgbanaka

Silicon Carbide igwe akàrà

A na-akpọ Silicon carbide (SiC) dị ka carborundum, nke a na-eji ájá quartz, petroleum coke (ma ọ bụ coal coke), ibe osisi (nke ekwesịrị ịgbakwunye mgbe ọ na-emepụta silicon carbide green) na ihe ndị ọzọ. Silicon carbide nwekwara obere ịnweta na okike, mulberry. N'oge a C, N, B na ndị ọzọ na-abụghị oxide elu technology refractory akụrụngwa, silicon carbide bụ otu n'ime ndị kasị ọtụtụ ebe na echekwa ihe, nke nwere ike na-akpọ ọla nchara ájá ma ọ bụ refractory ájá. Ka ọ dị ugbu a, a na-ekewa mmepụta nke silicon carbide na silicon carbide na silicon carbide na-acha akwụkwọ ndụ akwụkwọ ndụ, nke abụọ bụ kristal hexagonal nwere oke 3.20 ~ 3.25 na microhardness nke 2840 ~ 3320kg / m².

A na-ekewa ngwaahịa silicon carbide n'ụdị dị iche iche dabere na mpaghara ngwa dị iche iche. A na-ejikarị ya eme ihe ọzọ. Dịka ọmụmaatụ, silicon carbide bụ ezigbo ihe maka silicon carbide mechanical akara n'ihi ezigbo nguzogide corrosion nke kemịkalụ ya, ike dị elu, isi ike dị elu, nkwụsi ike dị mma, obere ọnụọgụ esemokwu na oke okpomọkụ.

Enwere ike kewaa mgbanaka akara SIC na mgbanaka static, mgbanaka na-akpụ akpụ, mgbanaka dị larịị na ihe ndị ọzọ. Enwere ike ịme silicon silicon ka ọ bụrụ ngwaahịa carbide dị iche iche, dị ka mgbanaka silicon carbide rotary, silicon carbide stationary oche, silicon carbide bushes, na ihe ndị ọzọ, dị ka ihe pụrụ iche chọrọ nke ndị ahịa. A pụkwara iji ya mee ihe na ihe graphite, na ọnụ ọgụgụ esemokwu ya dị ntakịrị karịa alumina seramiiki na alloy siri ike, ya mere enwere ike iji ya na uru PV dị elu, karịsịa na ọnọdụ acid siri ike na alkali siri ike.

Esemokwu mbelata nke SIC bụ otu n'ime uru dị mkpa dị n'iji ya rụọ ọrụ na akara igwe. Ya mere SIC nwere ike iguzogide iyi na ịdọka mma karịa ihe ndị ọzọ, na-agbatị ndụ nke akara. Na mgbakwunye, mbelata esemokwu nke SIC na-ebelata ihe achọrọ maka mmanu mmanu. Enweghị mmanu mmanu na-ebelata ohere nke mmetọ na corrosion, meziwanye arụmọrụ na ntụkwasị obi.

SIC nwekwara nnukwu nguzogide iyi. Nke a na-egosi na ọ nwere ike ịtachi obi n'iji ya eme ihe n'emebighị ma ọ bụ mebie. Nke a na-eme ka ọ bụrụ ihe zuru oke maka ojiji nke na-achọ ọkwa dị elu nke ntụkwasị obi na ịdịte aka.

Enwere ike ịsacha ya ọzọ ma na-egbuke egbuke ka e wee megharịa akara ọtụtụ ugboro n'oge ndụ ya. A na-ejikarị ya eme ihe n'ụzọ dị iche iche, dị ka na nchikota igwe maka ezigbo nguzogide corrosion kemịkalụ, ike dị elu, isi ike dị elu, nkwụsi ike dị mma, obere ọnụọgụ esemokwu na nguzogide okpomọkụ dị elu.

Mgbe ejiri ya maka ihu akara igwe, silicon carbide na-arụpụta arụmọrụ ka mma, ndụ akara na-abawanye, ọnụ ahịa mmezi dị ala, yana ọnụ ala na-agba ọsọ maka ngwa ngbanwe dị ka turbines, compressors, na nfuli centrifugal. Silicon carbide nwere ike inwe ihe dị iche iche dabere n'otú e siri rụọ ya. A na-emepụta mmeghachi omume silicon carbide site na ijikọ ihe ndị dị na silicon carbide na ibe ha na usoro mmeghachi omume.

Usoro a anaghị emetụta ọtụtụ n'ime ihe ndị dị na anụ ahụ na nke okpomọkụ nke ihe ahụ, agbanyeghị na ọ na-amachi nguzogide kemịkalụ nke ihe ahụ. Kemịkalụ a na-ahụkarị bụ nsogbu bụ caustics (na kemịkalụ pH ndị ọzọ dị elu) na acid siri ike, ya mere, a gaghị eji silicon carbide na-emeghachi omume na ngwa ndị a.

Batara mmeghachi omume-sinteredsilicon carbide. N'ime ihe ndị dị otú ahụ, a na-ejupụta pores nke ihe mbụ SIC na usoro nke infiltration site na-ere ọkụ silicon ọla, si otú ahụ SiC nke abụọ na-apụta na ihe ahụ na-enweta ihe ndị pụrụ iche na-arụ ọrụ, na-aghọ ndị na-eguzogide ọgwụ. N'ihi ntakịrị mbelata ya, enwere ike iji ya na-emepụta akụkụ buru ibu ma dị mgbagwoju anya na nso nso. Otú ọ dị, ọdịnaya silicon na-egbochi oke okpomọkụ na-arụ ọrụ na 1,350 Celsius C, nguzogide kemịkalụ na-ejedebekwa ihe dịka pH 10. A naghị atụ aro ihe ahụ maka iji mee ihe na gburugburu alkaline ike.

EjikọtaraA na-enweta silicon carbide site n'inweta granulate SIC mara mma nke ọma na okpomọkụ nke 2000 Celsius iji mepụta njikọ siri ike n'etiti ọka nke ihe ahụ.
Nke mbụ, lattice na-eto eto, mgbe ahụ, porosity na-ebelata, n'ikpeazụkwa, njikọ dị n'etiti mkpụrụ osisi. N'ime usoro nhazi dị otú ahụ, mbelata dị ukwuu nke ngwaahịa na-eme - ihe dịka 20%.
Mgbanaka akara SSIC na-eguzogide ọgwụ niile. Ebe ọ bụ na ọ dịghị silicon ọla dị na nhazi ya, enwere ike iji ya na okpomọkụ ruo 1600C na-emetụtaghị ike ya.

Njirimara

R-SiC

S-SiC

Ọgba aghara (%)

≤0.3

≤0.2

Njupụta (g/cm3)

3.05

3.1-3.15

Isi ike

110-125 (HS)

2800 (kg/mm2)

Modulus Elastic (Gpa)

≥400

≥410

Ọdịnaya SiC (%)

≥85%

≥99%

Ọdịnaya (%)

≤15%

0.10%

Ehulata Ike (Mpa)

≥350

450

Ike mkpakọ (kg/mm2)

≥2200

3900

Ọnụọgụ nke mgbasawanye okpomọkụ (1/℃)

4.5 × 10-6

4.3 × 10-6

Nguzogide okpomọkụ (na ikuku) (℃)

1300

1600

 

Mgbanaka igwe TC

TC igwe akara

Ihe TC nwere njirimara nke ike siri ike, ike, nkwụsị nke abrasion na nguzogide corrosion. A maara ya dị ka "Eze ụlọ ọrụ". N'ihi arụmọrụ ya dị elu, a na-ejikarị ya eme ihe na ụlọ ọrụ agha, ikuku ikuku, nhazi ígwè ọrụ, ígwè ọrụ ígwè, mkpọpu mmanụ, nkwurịta okwu electronic, ije na ubi ndị ọzọ. Dịka ọmụmaatụ, na nfuli, compressors na agitators, a na-eji mgbanaka carbide Tungsten mee ihe dị ka akara akara. Ezigbo nguzogide abrasion na ike siri ike na-eme ka ọ dị mma maka imepụta akụkụ ndị na-eyi uwe na-ekpo ọkụ na okpomọkụ dị elu, esemokwu na corrosion.

Dị ka ihe mejupụtara kemịkal ya na njirimara ojiji ya si dị, TC nwere ike kewaa ụzọ anọ: tungsten cobalt (YG), tungsten-titanium (YT), tungsten titanium tantalum (YW), na titanium carbide (YN).

Tungsten cobalt (YG) hard alloy mejuputara WC na Co.

Stelite (YT) mejupụtara WC, TiC na Co. N'ihi mgbakwunye nke TiC na alloy, a na-eme ka nguzogide iyi ya ka mma, mana ike na-ehulata, arụmọrụ na-egweri na conductivity thermal ebelatala. N'ihi na ọ na-agbaji n'okpuru obere okpomọkụ, ọ dị mma maka ngwa ngwa ngwa ngwa ngwa ngwa ngwa ngwa ọ bụghị maka nhazi nke ihe ndị na-egbuke egbuke.

Tungsten titanium tantalum (niobium) cobalt (YW) na-agbakwunye na alloy iji mee ka okpomọkụ dị elu, ike na nkwụsị nke abrasion site na nha kwesịrị ekwesị nke tantalum carbide ma ọ bụ niobium carbide. N'otu oge ahụ, a na-emeziwanye ike ahụ site na ịrụ ọrụ ịkpụcha nke ọma. A na-ejikarị ya eme ihe maka ịkpụ ihe siri ike na ịcha oge.

Klas titanium nke carbonized (YN) bụ ihe siri ike nke nwere akụkụ siri ike nke TiC, nickel na molybdenum. Uru ya bụ ike siri ike dị elu, ikike mgbochi njikọ, mgbochi - iyi ọnwa na ikike mgbochi oxidation. N'ebe okpomọkụ kariri ogo 1000, a ka nwere ike ịme ya. Ọ na-adabara na-emecha na-aga n'ihu nke alloy ígwè na quenching ígwè.

ihe nlereanya

ọdịnaya nickel (wt%)

njupụta (g/cm²)

ike (HRA)

ike ekwe (≥N/mm²)

YN6

5.7-6.2

14.5-14.9

88.5-91.0

1800

YN8

7.7-8.2

14.4-14.8

87.5-90.0

2000

ihe nlereanya

ọdịnaya cobalt (wt%)

njupụta (g/cm²)

ike (HRA)

ike ekwe (≥N/mm²)

YG6

5.8-6.2

14.6-15.0

89.5-91.0

1800

YG8

7.8-8.2

14.5-14.9

88.0-90.5

1980

YG12

11.7-12.2

13.9-14.5

87.5-89.5

2400

YG15

14.6-15.2

13.9-14.2

87.5-89.0

2480

YG20

19.6-20.2

13.4-13.7

85.5-88.0

2650

YG25

24.5-25.2

12.9-13.2

84.5-87.5

2850